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Kinetics Modeling of Gas Hydrate Decomposition of Methane-Ethane Mixture
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Kinetics Modeling of Gas Hydrate Decomposition of Methane-Ethane Mixture
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Abstract
In this study, the kinetics of gas hydrate decomposition of methane-ethane mixture has been predicted. The thermodynamics natural path in chemical reaction kinetics was used for modeling of the hydrate decomposition rate in a volume constant process. This method has thermodynamic and macroscopic view and the basic idea is that a unique path only exists for each experiment that affinity decay. The gas mixtures in 0.099, 0.199 and 0.314 mole fraction of methane have been studied. The results show there is good agreement with experimental data. Also the parameters of model that were calculated in operating constant temperature of 277.15 k, are depending on the gas component concentration in the mixtures. The time to attain equilibrium of hydrate decomposition process increases by means of increase methane in the mixture. Index term- Methane, Ethane, Decomposition Kinetics, Chemical Affinity, Gas Hydrate.
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International Category Code (ICC):
ICC-0202
P. Naeiji, F. Varaminian
International Article Address (IAA):
IAA.ZONE/en8313en
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